Abstract
In the coordination field calculation of rare-earth ions, the D2 point group basis functions were classified and labeled according to the relation of the point group chain R(3)* ⊃ O* ⊃ ⊃ The perturbation matrix elements of the coordination field for the rare-earth complexes in the dihedral field were systematically derived with the double-sphere coordination point-charge field (DSCPCF) model and the irreducible tensor operator method and the corresponding computer program DSF. D was compiled. The DSCPCF perturbation energy levels of Eu(phen)2(NO3)3 and Eu(PU)8(NO3)3 were calculated, and the fluorescence spectra were assigned. The calculated results agree with the observed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
