Abstract
HighlightsA novel Ni(OH)2-based catalyst with ultralow Ni–Ni coordination is produced, exhibiting high activity (100 mA cm−2 at 1.39 V for methanol oxidation reactions) and outstanding stability in an industrial concentration electrolyte (over 500 mA cm−2 in 6 M KOH).Mechanistic studies show that the improved kinetics and durability are primarily due to ultralow Ni–Ni coordination, 3D-networking structures and the Mo dopant.
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