Abstract

Abstract The reactions of some aroylhydrazones (HL) with cobalt(II) salts were investigated and chelates of the types [Co(HL) 2 X 2 ] and [Co(L) 2 ] were isolated. Analytical data, infrared studies, magnetic moments and solution spectra as well as some conductivity measurements were used to characterise these chelates. The [Co(HL) 2 X 2 ] chelates were found to possess octahedral configuration in solid state but dissociate in DMF solutions. Attempts were made to identify the dissociation products. A dimeric pentacoordinate structure was tentatively assigned for the neutral [Co ( L ) 2 ] chelates.

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