Abstract
Infrared spectra of some triarylphosphine and diphosphine complexes of gallium (III) chloride, bromide, and iodide have been recorded in the range 600–200 cm−1 and assignments of gallium–halogen stretching vibrations made. The number and frequencies of the ν (Ga–X) vibrations are consistent with monomeric structures for the triarylphosphine complexes in the solid state. Possible structures for the diphosphine complexes are discussed.
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