Abstract
Fe(CO)4(Ph2Ppy-P) (1), prepared by the oxygen-atom transfer reaction, reacted as an organometallic bidentate ligand with HgX2 (X = Cl, I) to form binuclear complexes containing a Fe—Hg bond and treatment of the organometallic tridentate ligand trans-Fe (PhPMepy)2(CO)3 (2) with M(CO)6 (M = Cr, Mo), M(SCN)2 (M = Zn, Cd, Co, Ni, Mo), HgX2 (X = Cl, I) and CdCl2 also afforded binuclear complexes including a Fe—M bond. The crystal and molecular structures of the Fe-Hg complexes (CO)4Fe(μ-Ph2Ppy)Hg(μ-Cl) 2HgCl2 (3), (CO)3Fe(μ-PhPMepy)2Hg(μ-Cl)2HgCl2·1/2CH2Cl2 (5) and (CO)3Fe(μ-PhPMepy) 2Hg(μ-I)2HgI2· 3CH2Cl2 (6) have been determined. Copyright © 1996 Elsevier Science Ltd
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