Abstract
The problems of actinide molten salt coordination chemistry are considered in terms of spectroscopic parameters as functions of melt composition and temperature. Parameters connected with energy, intensity and fine structure of 5f-5f transitions have been obtained for molten alkali metal chlorides, fluorides and chloride-fluoride mixtures. The regularities of variation of both actinide-chlorine distances and actinide fluorocomplex stability have been studied.
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