Abstract
AbstractIn the past decades, great efforts have been devoted to the design and self‐assembly of discrete metal‐organic cages (MOCs). The further assembly of cages into advanced supramolecular materials is relatively less developed. Previously, we reported a water‐soluble Ti4L6 cage (L=embonate), which has been applied as the starting material to realize coordination assembly with different metal ions through two‐step reaction. In this work, by employing the Ti4L6 cages to assemble with Mn2+ ions in the presence of piperazine and melamine, a Ti4L6−Mn2 cage and a Z‐shaped Ti4L6−Mn2 chain structure have been synthesized and structurally characterized, respectively.
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