Abstract
We report a cooperative (i.e., nucleation-elongation) self-assembling process of a core-substituted naphthalenediimide induced by a catalyst-free amino-yne click reaction at 298 K. The self-assembling process was initiated immediately in the presence of nuclei (seeds). The combination of the click reaction and the seeded self-assembling process paves the way for precise control over supramolecular assemblies of electron-deficient π-systems.
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