Abstract
Separation of CO2 based on adsorption, absorption, and membrane techniques is a crucial technology necessary to address current global warming issues. Porous media are essential for all these approaches and understanding the nature of the porous structure is important for achieving highly efficient CO2 adsorption. Porous carbon is considered to be a suitable porous media for investigating the fundamental mechanisms of CO2 adsorption, because of its simple morphology and its availability in a wide range of well-defined pore sizes. In this study, we investigated the dependence of CO2 adsorption on pore structures such as pore size, volume, and specific surface area. We also studied slit-shaped and cylindrical pore morphologies based on activated carbon fibers of 0.6–1.7 nm and carbon nanotubes of 1–5 nm, respectively, with relatively uniform structures. Porous media with larger specific surface areas gave higher CO2 adsorption densities than those of media having larger pore volumes. Narrower pores gave higher adsorption densities because of deep adsorption potential wells. However, at a higher pressure CO2 adsorption densities increased again in nanopores including micropores and small mesopores. The optimal pore size ranges of CO2 adsorption in the slit-shaped and cylindrical carbon pores were 0.4–1.2 and 1.0–2.0 nm, respectively, although a high adsorption density was only expected for the narrow carbon nanopores from adsorption potentials. The wider nanopore ranges than expected nanopore ranges are reasonable when considering intermolecular interactions in addition to CO2–carbon pore interactions. Therefore, cooperative adsorption among CO2 in relatively narrow nanopores can allow for high density and high capacity adsorption.
Highlights
Emissions of CO2 are a serious global issue because of the contributions of CO2 to global warming as a major greenhouse gas
We conducted experiments and computations to study how CO2 adsorption properties depend on pore size and morphology using activated carbon fibers (ACFs) and Carbon nanotubes (CNTs)
Adsorption properties generally depend on specific surface area, pore volume, and pore size
Summary
Emissions of CO2 are a serious global issue because of the contributions of CO2 to global warming as a major greenhouse gas. Adsorption, absorption, and membrane separation can be used under ambient conditions These techniques depend on porous media such as activated carbon, porous silica, zeolites, and metal organic frameworks (Bhatia and Nguyen, 2011; Choi et al, 2009; D’Alessandro et al, 2010; Presser et al, 2011; Sevilla et al, 2011; Silvestre-Albero and Rodrıguez-Reinoso, 2012; Silvestre-Albero et al, 2011; Wahby et al, 2010; Xia et al, 2011; Yang et al, 2008). The mesopore volumes were calculated by subtraction of the micropore volumes from the total pore volumes
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