Abstract
Conversion of the diamagnetic salt of the nonamethylferrocenylcarbenium primary cation into the paramagnetic salt of bis(nonamethylferroceniumyl)ethane has been studied by high-resolution NMR in solution and, mainly, by spin—lattice and spin—spin relaxation in solids. For the first time the dependence of the conversion rate on the nature of the anions BF 4 −, PF 6 −, AlBr 4 − and the aggregate state of the sample has been established. Possible mechanisms of the conversion are discussed.
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