Abstract
AbstractThe reaction of ferriohydridosilanes Cp(CO)(L)Fe–SiR2H (R = Me, t‐Bu, Ph, o‐Tolyl; L = CO, Ph3P) 1a–e with dimethyldioxirane (as an acetone solution) leads directly to the corresponding ferriosilanols Cp(CO)(L)Fe–SiR2OH 2a–e in moderate to excellent yields.
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