Abstract
Conversion of dissolved P by ferric sulfate into a particulate form sparingly available to algae was studied in 15 ditches in Finland using stand-alone dispensers for ferric sulfate administration. Ferric sulfate typically converted 60–70 % of dissolved P into iron-associated form, a process which required 250–650 kg per kg dissolved P. Mean cost was 160 EUR per kg P converted (range 20–400 EUR kg−1). The costs were lowest at sites characterized by high dissolved P concentrations and small catchment area. At best, the treatment was efficient and cost-effective, but to limit the costs and the risks, ferric sulfate dispensers should only be installed in small critical source areas.
Highlights
To combat eutrophication of surface waters, the EU Water Framework Directive (Directive 2000/60/EC) prescribes restoration or enhancement of the chemical and ecological status of water bodies
Because agriculture is currently considered a major contributor to phosphorus (P) loading of surface waters (e.g., HELCOM 2009), agricultural sources need to be included in P mitigation plans
We examined the use of a simple type of ferric sulfate dispenser for reducing the concentrations of dissolved P in stream runoff, using as test sites 15 agricultural ditches in SW Finland
Summary
To combat eutrophication of surface waters, the EU Water Framework Directive (Directive 2000/60/EC) prescribes restoration or enhancement of the chemical and ecological status of water bodies. A site with high soil P concentrations and a hydrological connection to a stream through a ditch network or tile drainage system will contribute to the total P loads in a body of water to much greater extent than reflected by its proportion of catchment area. Dissolved P concentrations in runoff tend to be elevated as a result of long-term P accumulation in soil. The dissolved P pool is generally considered to be totally available for biological utilization (Ekholm and Krogerus 2003), whereas much of the P present as particulate P (PP) may be practically inert in the short term (Sonzogni et al 1982). Particulate P can partly enter the biological cycle under special circumstances (Lehtoranta et al 2015), but when aiming to limit the amount of P readily available to aquatic algae, dissolved P is logically the first priority for remedial actions because it can immediately trigger algal growth in P-limited waters
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