Abstract

Conversion of dissolved P by ferric sulfate into a particulate form sparingly available to algae was studied in 15 ditches in Finland using stand-alone dispensers for ferric sulfate administration. Ferric sulfate typically converted 60–70 % of dissolved P into iron-associated form, a process which required 250–650 kg per kg dissolved P. Mean cost was 160 EUR per kg P converted (range 20–400 EUR kg−1). The costs were lowest at sites characterized by high dissolved P concentrations and small catchment area. At best, the treatment was efficient and cost-effective, but to limit the costs and the risks, ferric sulfate dispensers should only be installed in small critical source areas.

Highlights

  • To combat eutrophication of surface waters, the EU Water Framework Directive (Directive 2000/60/EC) prescribes restoration or enhancement of the chemical and ecological status of water bodies

  • Because agriculture is currently considered a major contributor to phosphorus (P) loading of surface waters (e.g., HELCOM 2009), agricultural sources need to be included in P mitigation plans

  • We examined the use of a simple type of ferric sulfate dispenser for reducing the concentrations of dissolved P in stream runoff, using as test sites 15 agricultural ditches in SW Finland

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Summary

Introduction

To combat eutrophication of surface waters, the EU Water Framework Directive (Directive 2000/60/EC) prescribes restoration or enhancement of the chemical and ecological status of water bodies. A site with high soil P concentrations and a hydrological connection to a stream through a ditch network or tile drainage system will contribute to the total P loads in a body of water to much greater extent than reflected by its proportion of catchment area. Dissolved P concentrations in runoff tend to be elevated as a result of long-term P accumulation in soil. The dissolved P pool is generally considered to be totally available for biological utilization (Ekholm and Krogerus 2003), whereas much of the P present as particulate P (PP) may be practically inert in the short term (Sonzogni et al 1982). Particulate P can partly enter the biological cycle under special circumstances (Lehtoranta et al 2015), but when aiming to limit the amount of P readily available to aquatic algae, dissolved P is logically the first priority for remedial actions because it can immediately trigger algal growth in P-limited waters

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