Abstract
Treatment of (2-methyl-1-azabuta-1,3-diene)tricarbonyliron(0) complexes with lithium diethylamide followed by a methyl iodide, benzyl bromide or allyl bromide quench leads to the formation of tertiary (enamine)tricarbonyliron(0) complexes in good yield. The crystal structures of two complexes, (2-( N-methyl- N-(4-methoxyphenyl)amino)-4-phenylbuta-1,3-diene)tricarbonyliron(0) ( 19) and (2-( N-allyl- N-isopropylamino)-4-phenylbuta-1,3-diene)tricarbonyliron(0) ( 24) are reported.
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