Abstract

To improve the power conversion efficiency of polymer solar cells, the blended P3HT:PCBM:pentacene active layer was used to balance hole–electron mobility and roughen surface. Using space-charged-limited current model to analyze the hole-only devices and the electron-only devices, the P3HT:PCBM:pentacene (weight ratio=1:0.8:0.09) active layer exhibited balance hole–electron mobility. Compared with the power conversion efficiency of 3.46% of the conventional polymer solar cells using P3HT:PCBM (1:0.8) active layer, the power conversion efficiency of 4.42% was obtained. In other words, the power conversion efficiency was improved about 27.5%.

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