Abstract
The reactions of [CpRu(CO) 2] 2 with CX 4 (X = Cl, Br) were found to take place under indoor light conditions as well as in the dark to afford CpRu(CO) 2X (X = Cl, Br) in excellent yields. Another convenient synthetic route to such ruthenium halide complexes involves the reaction of CpRu(CO) 2H, prepared “in situ” from Ru 3(CO) 12 and cyclopentadiene, with CX 4 (X = Cl, Br).
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