Controls on copper and gold endowments of porphyry deposits

Abstract

<p>Porphyry deposits are the major natural source of copper and a significant natural source of gold, which are essential metals for our society. Porphyry deposits form at convergent margins both during subduction (syn-subduction, Andean-type deposits) and in post-subduction to post-collision and extensional geodynamic settings (post-subduction deposits). Syn-subduction porphyry deposits are typically associated with calc-alkaline magmas often characterized by high Sr/Y values (~50-150). In contrast, post-subduction deposits are mostly associated with variably alkaline magmas having lower Sr/Y values (~25-75). The reasons of the association of porphyry deposits with magmas having different geochemical affinities and of their widely variable Cu and Au endowments (from <1 to >100 Mt for Cu and from few tens to >2500 tons for gold) remain unconstrained.</p><p>Porphyry Cu-Au deposits define two distinct trends in plots of Au versus Cu endowments and Au endowment versus duration of the ore process (Chiaradia, 2020): one trend (Cu-rich) is characterized by steep Cu/Au endowment values (Cu/Au~250000) and an average low rate of Au deposition (~100 tons Au/Ma); the other trend (Au-rich) is characterized by low Cu/Au endowment values (Cu/Au~12500) and an average high rate of gold deposition (~4500 tons Au/Ma). The Au-rich trend is defined to the greatest extent by seven, alkaline magma-related, porphyry gold systems (>1100 tons Au) and subordinately by numerous calc-alkaline systems (<1300 tons Au). The Cu-rich trend is defined only by calc-alkaline magma-related porphyry systems.</p><p>Modelling of petrological and metal precipitation processes using a Monte Carlo approach suggests that, whereas Cu-rich porphyries are formed by large volumes of magma, Au-rich porphyries result from a better precipitation efficiency of Au. The specific association of the largest Au-rich porphyry deposits with variably alkaline magmas also points out that alkaline magma chemistry favours an upgrade of Au endowments.</p><p> </p><p><strong>References</strong></p><p><em>Chiaradia, M. (2020) Gold endowments of porphyry deposits controlled by precipitation efficiency. Nature Communications 11, 248, https://doi.org/10.1038/s41467-019-14113-1.</em></p>