Controlling the ductile to brittle transition in Fe–9%Cr ODS steels

Abstract

Probably the most important range of materials for consideration as the blanket material for the tokamak design for fusion reactors ITER and DEMO is the high alloy Fe–9Cr oxide dispersion strengthened ferritic steels. Ferritic steels possess exceptional thermal conductivity and low thermal expansion and are resistant to void swelling. Their main drawback is high ductile to brittle transition temperatures, particularly in the oxide dispersion strengthened versions. This paper describes attempts to reduce the DBTT in an un-irradiated ferritic steel by a novel heat treatment procedure. New batches of high alloy Fe–9Cr oxide dispersion strengthened (Eurofer) ferritic steel have been produced by a powder metallurgy route, and relatively homogeneous material has been produced by hot isostatic pressing (HIP). Mini-Charpy test specimens were made from materials which had been subjected to a matrix of heat treatments with varying solution treatment temperature (ST), cooling rate from the ST temperature, and tempering treatment. The initial DBTT was in the range of 150–200°C (423–473K). Downward shifts of up to approximately 200°C (473K) have been observed after solution treatment at 1300°C (1573K) followed by slow cooling. This paper describes the microstructure of this material, and discussion is made of the likely microstructural factors needed to produce these DBTT downward shifts.