Abstract
Controlling hybrid material properties by simple monomer design offers an elegant pathway to prepare thermoset adhesives with tunable properties. Herein, biobased hybrid polyhydroxyurethane/polyepoxy is prepared starting from partially carbonated cashew nut shell epoxy derivatives (NC514) and m-xylene diamine (MXDA). The curing reactions, that is, epoxy-amine and cyclic carbonate aminolysis, monitored by ATR-IR spectroscopy at 50°C are found to be concomitant yielding highly homogeneous materials. Hybrid networks are extensively characterized by swelling tests, TGA, DMA, DSC, tensile tests, rheology, and lap-shear-test on aluminum substrates. The introduction of hydroxyurethane moieties within the epoxy-amine networks enhanced the adhesion properties (up to 20% compare to neat epoxy resins) by combining hydrogen bonding capability and vitrimeric properties (thermoset able to flow). Rheological characterizations and reprocessing tests demonstrated that hybrid adhesives with up to 47 mol% of cyclic carbonate groups are capable of covalent exchange (internally catalyzed by tertiary amine) while keeping similar thermomechanical properties and enhanced adhesion strength compare to the permanent epoxy network.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
