Controlling Foam Morphology of Poly(methyl methacrylate) via Surface Chemistry and Concentration of Silica Nanoparticles and Supercritical Carbon Dioxide Process Parameters

Abstract

Polymer nanocomposite foams have received considerable attention because of their potential use in advanced applications such as bone scaffolds, food packaging, and transportation materials due to their low density and enhanced mechanical, thermal, and electrical properties compared to traditional polymer foams. In this study, silica nanofillers were used as nucleating agents and supercritical carbon dioxide as the foaming agent. The use of nanofillers provides an interface upon which CO2 nucleates and leads to remarkably low average cell sizes while improving cell density (number of cells per unit volume). In this study, the effect of concentration, the extent of surface modification of silica nanofillers with CO2‐philic chemical groups, and supercritical carbon dioxide process conditions on the foam morphology of poly(methyl methacrylate), PMMA, were systematically investigated to shed light on the relative importance of material and process parameters. The silica nanoparticles were chemically modified with tridecafluoro‐1,1,2,2‐tetrahydrooctyl triethoxysilane leading to three different surface chemistries. The silica concentration was varied from 0.85 to 3.2% (by weight). The supercritical CO2 foaming was performed at four different temperatures (40, 65, 75, and 85°C) and between 8.97 and 17.93 MPa. By altering the surface chemistry of the silica nanofiller and manipulating the process conditions, the average cell diameter was decreased from 9.62 ± 5.22 to 1.06 ± 0.32 μm, whereas, the cell density was increased from 7.5 ± 0.5 × 108 to 4.8 ± 0.3 × 1011 cells/cm3. Our findings indicate that surface modification of silica nanoparticles with CO2‐philic surfactants has the strongest effect on foam morphology.