Controlling electroosmotic flow by polymer coating: a dissipative particle dynamics study

Abstract

We have performed dissipative particle dynamics (DPDs) simulations of electroosmotic flow (EOF) through a polymer-grafted nanopore. In this model, charged particles including salt ions and counterions are not included explicitly, and EOF is created using an effective boundary condition. The screening effect of polymer layer on EOF is investigated in detail under different solvent qualities and boundary electroosmotic velocities. Results show that the solvent quality has a significant effect on the conformational properties of polymer chains and the flow characteristics of the solvent. The polymer layer undergoes a collapsed transition when decreasing the solvent quality from good to poor. Under different solvent qualities, enhancing the EOF leads to a different variation tendency of the layer thickness. The solvent-induced permeability change is inconsistent with the steady velocity away from the surface. The minimum value of the solvent permeability occurs at an intermediate solvent quality. However, the layer thickness drops gradually to a smallest value (corresponding to the largest effective pore radius) in the poor solvent condition. It is also found that the polymer inclination and stretching length exhibit a complex behavior under the combined effect of solvent quality and electroosmosis-induced shear.