Controlled Room Temperature Synthesis of CoFe2O4 Nanoparticles through a Block Copolymer Nanoreactor Route

Abstract

The synthesis and characterization of well-dispersed, CoFe2O4 nanoparticles within a polymer matrix at room temperature are reported. Comparable inorganic synthetic methods require heating at high temperatures in order to produce this particular mixed-metal oxide composition. Our modification of prior reported templating schemes using block copolymers consists of introducing a mixture of metal salts to a polymer solution before any microphase separation of the block copolymer constituents can occur, thus allowing fast diffusion of metals to the functional polymer backbone. The diblock copolymer matrix was synthesized using ring-opening metathesis polymerization of norbornene derivatives. The self-assembly of the mixed-metal oxide within the polymer template was achieved at room temperature by introducing a mixture of FeCl3 and CoCl2 into one of the functional polymer blocks and by subsequent processing of the copolymer by wet chemical methods to substitute the chlorine atoms with oxygen. CoFe2O4 nanoparti...