Abstract

Controlled Radical Polymerization (CRP) such as Atom Transfer Radical Polymerization (ATRP) or Nitroxide Mediated Radical Polymerization (NMRP), can be used to obtain various well defined rod-coil conjugated diblock or triblock copolymers having well controlled opto-electronic properties. These copolymers are soluble in common organic solvents and can be self-organized giving rise at various nm length scale and thermodynamically stable structures. They show promising opto-electronic properties and fulfil the basic morphological requirements towards the fabrication of efficient flexible organic electronic devices.

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