Abstract
Preparation of new tailor-made phosphorus-containing polydiene materials via controlled radical copolymerization of dimethyl 1,3-butadiene-1-phosphonate (BPMe) with chloroprene (CP) or isoprene (IP), by using, respectively, AIBN or an alkoxyamine derivative as initiator, is reported. The corresponding materials have been microstructurally characterized by 1H and 31P NMR spectroscopies.
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