7-days of FREE Audio papers, translation & more with Prime
7-days of FREE Prime access
7-days of FREE Audio papers, translation & more with Prime
7-days of FREE Prime access
https://doi.org/10.1021/ma00048a008
Copy DOIJournal: Macromolecules | Publication Date: Oct 1, 1992 |
Citations: 121 |
It is shown that certain combinations of lithium and aluminum alkyl enable polymerizations of alkyl methylmethacrylate to be carried out at elevated temperatures. Both the lithium and aluminum components must contain alkyl groups which have cross-sectional areas as large as possible. Moreover, these initiators are only effective in hydrocarbon solvents in which they are soluble. In hydrocarbon solvents the separation between the anionic and cationic components are minimized and the high cross-sectional area of the latter screens the propagating terminus of the polymer chain from side reactions. Molecular weights in the range 2000-150000 were obtained with dispersions close to that described by the Poisson distribution
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.