Abstract

Functional Polyaniline (PANI) nanotubes are easily synthesized in high yield by an in situ polymerization using a fibrillar complex of acid orange II (AO II) and FeCl3as a template. During the process, the complex templates help direct the growth of fibrillar PANI on their surfaces, resulting in the formation of composite micro/nanofibers of PANI. After polymerization, by the post-treatment of removing templates in 1.0 M hydrochloric acid solution, PANI nanotubes with azo function and high electric conductivity of PANI are readily fabricated. The PANI nanotubes have about 150nm-300nm in diameter and several microns in length. At room temperature, the electric conductivity of PANI nanotubes is up to 10-1S/cm order of magnitude. The characterizations, including FTIR, UV-visible, XRD and TG, are presented.

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