Abstract

Ag-WO3 core-shell nanospheres (CSNSs) are fabricated for gas sensor applications. It is found that the sensor based on Ag-WO3 CSNSs dramatically improve the sensor performance towards alcohol vapor, with significantly lower optimum working temperature (260°C) and superior detection limit (0.20ppm) comparing to pure WO3 hollow nanospheres (HNSs). The Ag-WO3 sensor displays an ultrahigh sensitivity under visible light illumination. When illuminated under a 150W xenon arc light source, the response is increased from 62 to 160, the optimum working temperature is reduced from 260 to 190°C, and the detection limit is improved from 0.20 to 0.032ppm. This work may offer an attractive strategy to improve sensitivity of light-enhanced plasmonic metal-oxide based gas sensors.

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