Controllable Multicolor Upconversion Luminescence of Lanthanide Doped NaGdF4 Nanocrystals Through Single Laser Excitation at 980 nm

Abstract

Room temperature multicolor Upconversion (UC) luminescence in Yb3+, Tm3+, Er3+ ions doped NaGdF4 nanocrystals have been successfully synthesized by a hydrothermal method. As-prepared nanocrystals are highly crystalline and well-dispersed in cyclohexane to form stable and clear colloidal solutions, which demonstrates strong emission properties with a single laser excitation at 980 nm. The multicolor light consists of blue, green, and red UC radiations that correspond to transitions 1G4 --> 3H6 of Tm3+, 2H(11/2)/4S(3/2) --> 4I(15/2), and 4F(9/2) --> 4I(15/2) of Er3+ ions, respectively. The UC mechanisms were proposed based on spectral, kinetic, and pump power dependence analyses.