Abstract
Control of the non-adiabatic photodissociation dynamics of CH 2BrCl into CH 2Br + Cl or CH 2Cl + Br has been achieved using a driving few-cycle IR laser pulse followed by a control UV pulse. Employing two-dimensional time-dependent wave packet propagations on a three-state diabatic model we show that the branching ratio leading to the dissociation of the stronger bond (C–Cl) can be increased by an order of magnitude.
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