Control of morphology and composition of self-organized zirconium titanate nanotubes formed in (NH 4) 2SO 4/NH 4F electrolytes

Abstract

We investigated the formation of self-organized zirconium titanate nanotubes by anodizing a Ti-35Zr alloy in 1 M (NH 4) 2SO 4 + 0.1–2.0 wt.% NH 4F electrolytes. The morphology and composition of the zirconium titanate nanotube are controlled by the applied electrochemical conditions. The outer diameter of nanotubes is controlled by the anodization potential in the range between 1 and 100 V (versus Ag/AgCl). Tubes with diameters from 14 to 470 nm can be grown. The nanotube length correlates with the anodic charge up to a length where significant dissolution of the nanotube layer is observed. The wall thickness, composition of the nanotubes and porosity of the nanotube layer are significantly affected by the fluoride ion concentration. The length limiting factor of the nanotube growth is found to be the diffusion of ionic species in the electrolyte.