Abstract
We review the basic principles of quantized transition state control of microcanonical ensemble rate constants and state-selected rate constants. Selected examples are presented for the H+H 2 and O+H 2 reactions. The following aspects are emphasized: (i) We can calculate accurate quantal microcanonical rate constants up to high energies. (ii) These rate constants show resolvable structure which may be attributed to quantized transition states. (iii) The energy dependence of the microcanonical rate constants can be explained quantitatively using a transition state plus tunneling model based on these quantizod transition states
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