Abstract
Iron mixed-valence complex, (n-C3H7)4N[FeIIFeIII(dto)3] (dto = C2O2S2), shows a charge transfer phase transition around 120 K and a ferromagnetic transition at 6.5 K. In order to control the charge transfer phase transition by changing the cation size, we synthesized (n-C n H2n+1)4N[FeIIFeIII(dto)3] (n = 3−6) and investigated the charge transfer phase transition by means of 57Fe Mossbauer spectroscopy. The charge transfer phase transition takes place around 120 K for n = 3 and 4, while it does not take place between 300 K and 4 K for n = 5 and 6.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
