Contributions of Ammonia to High Concentrations of PM2.5 in an Urban Area

Junsu Park,Mijung Song,Haeri Kim,Soontae Kim,Eunhye Kim,Sangmin Oh,Yong Pyo Kim

doi:10.3390/atmos12121676

Abstract

Atmospheric ammonia (NH3) plays a critical role in PM2.5 pollution. Data on atmospheric NH3 are scanty; thus, the role of NH3 in the formation of ammonium ions (NH4+) in various environments is understudied. Herein, we measured concentrations of NH3, PM2.5, and its water-soluble SO42−, NO3−, and NH4+ ions (SNA) at an urban site in Jeonju, South Korea from May 2019 to April 2020. During the measurement period, the average concentrations of NH3 and PM2.5 were 10.5 ± 4.8 ppb and 24.0 ± 12.8 μg/m3, respectively, and SNA amounted to 4.3 ± 3.1, 4.4 ± 4.9, and 1.6 ± 1.8 μg/m3, respectively. A three-dimensional photochemical model analysis revealed that a major portion of NH3, more than 88%, originated from Korea. The enhancement of the ammonium-to-total ratio of NH3, NHX (NHR = [NH4+]/[NH4+] + [NH3]) was observed up to ~0.61 during the increase of PM2.5 concentration (PM2.5 ≥ 25 μg/m3) under low temperature and high relative humidity conditions, particularly in winter. The PM2.5 and SNA concentrations increased exponentially as NHR increased, indicating that NH3 contributed significantly to SNA formation by gas-to-particle conversion. Our study provided experimental evidence that atmospheric NH3 in the urban area significantly contributed to SNA formation through gas-to-particle conversion during PM2.5 pollution episodes.

Highlights

Global emissions of NH3 have annually increased from an estimated 1.9 Tg in the 1960s to 16.7 Tg in 2010 [1]
Reports have indicated that the main source of atmospheric NH3 at the global scale is agricultural activities involving livestock, fertilizers, soil, and crops [2,3,4,5]; these activities accounted for approximately 60% of the total NH3 emitted from Asia in the
SNA to determine the effect of NH3 on PM2.5 pollution at an urban area, Jeonju, South Korea from May 2019 to April 2020

Summary

Introduction

Global emissions of NH3 have annually increased from an estimated 1.9 Tg in the 1960s to 16.7 Tg in 2010 [1]. NH3 is important because it can contribute to the acidification of ecosystems [6,7] It plays a critical role in chemical reactions in the atmosphere, where its conversion to particulate ammonium can lead to high concentrations of particulate matter [8,9,10,11,12,13,14]. These particulate ammonium can influence air quality, visibility, and human health [15,16,17]. An average ambient NH3 concentration of ~36.2 ppb, with variations ranging from ~73.9 ppb in July to

Methods

Results

Conclusion