Abstract

The analysis of temperature dependences of magnetic moment of several new iron nitrosyl complexes in solid phase allowed the value of exchange interaction ( J) between two iron ions to be estimated in each type complexes and a systematic decrease of J together with the increase in the ESR linewidth with a distance between iron ions to be observed. It was found that exchange interaction in the complexes involves two components, namely, direct exchange interaction and indirect one transferred through organic ligands.

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