Abstract

The influence of the continuous phase viscosity (μc) on the diameter of styrene-divinylbenzene polymer beads was studied over a large range of viscosities at constant dissipated power. This study was based on the inertial breakup and viscous shear breakup theories for a stirred dispersion. These two theoretical models were compared with an experiment for the two highly viscous agents sucrose and acacia gum [dispersed and continuous phase viscosities (μd, μc) = 10−3 < μd/μc < 1]. We found that the maximum diameters of the polymer beads could not be described by an inertial breakup. The maximum diameters were in good agreement with a viscous shear breakup model for the two viscous agents in turbulent and semilaminar flows. © 2000 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 39: 201–210, 2001

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