Continuous Growth of Carbon Nanotubes on Carbon Fiber Surface by Chemical Vapor Deposition Catalyzed by Cobalt with Thiourea

Abstract

The continuous preparation of carbon nanotubes (CNTs)/carbon fiber (CF) multiscale reinforcements was realized via one-step chemical vapor deposition (CVD) method. In order to alleviate the damage of CF caused by catalyst etching at high temperature, catalytic promoter was adopted to improve the activity of the catalyst, thus reducing the CVD temperature. By adjusting the cobalt-based catalyst system, the effects of thiourea concentration on the morphology, microstructure and tensile strength of CNTs/CF samples were systematically investigated. It was found that the length and quantity of CNTs were added as the thiourea concentration increased, and the graphitization degree of the sample increased at first because of the well-grown CNTs, and then decreased due to the formation of amorphous carbon. Moreover, the tensile strength of CNTs/CF multiscale reinforcements was improved, which derived from the enhanced defect repair function of synthesized CNTs. Remarkably, CNTs/CF-0.02 exhibited a high single-filament tensile strength value (up to 4.51 GPa), which was about 6.6% higher than that of Desized cf Besides, the crystal structure and composition of reduced catalysts were analyzed, confirming the successful sulfur doping into cobalt particles. Therefore, the work offers a facile, economical, and efficient route for manufacturing CNTs/CF multi-scale reinforcements at comparatively low temperature.