Abstract

The triticale grain has high nutritive value and good technological suitability. Triticale flour can be a valuable raw material for bread-making. The aim of this work was to determine the profile of phenolic acids in triticale grain of selected Polish cultivars and its products. Ultra-high-performance liquid chromatography (UPLC-PDA-MS/MS) was applied for separation and identification of these constituents. The grain of the examined triticale cultivars contained 13 phenolic acids, of which ferulic acid was determined in the largest amount and was constituted from 42–44% of the total content of phenolic acids in the grain. In addition, due to the large amounts of ferulic, di-ferulic, and sinapic acids, composition of the phenolic acids fraction in triticale grain of the tested cultivars varied in comparison with that of wheat and rye cultivars. In triticale flour, the number of phenolic acids was nearly 4 times lower than in the grain, as phenolic acids were removed along with bran, in which their proportion was almost 9 times higher than in the grain intended for grinding. The application of bran in the bread recipe resulted in a 3.5-fold increase in the fraction of phenolic acids compared to the bread produced from triticale flour without bran addition.

Highlights

  • The ESI-MS signals at m/z 137 and m/z 197 were identified as 4-hydroxybenzoic acid, 3-hydroxybenzoic acid, and syringic acid respectively, by comparing their retention time and MS spectra data with those of an authentic standard

  • Our studies demonstrated that triticale grain of the examined cultivars had slightly different composition of the phenolic acid fraction when compared to the results reported by the cited authors, referring to the content of phenolic acids (PAs) in the grains of parental species

  • Triticale grain is an important source of PAs

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Summary

Introduction

Academic Editors: Krystian Marszałek, Shuyi Li, Ireneusz Kapusta and Jose Manuel LorenzoReceived: 9 December 2020Accepted: 20 January 2021Published: 21 January 2021Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.Licensee MDPI, Basel, Switzerland.Attribution (CC BY) license (https://creativecommons.org/licenses/by/ 4.0/).Triticale (xTriticosecale Wittm. Ex A. Camus) is the first human-produced cereal obtained by crossing wheat (Triticum) and rye (Secale). Today, it is grown in many countries.

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