Content, mobility and transfer behavior of heavy metals in MSWI bottom ash in Zhejiang province, China

Abstract

Municipal solid waste incinerator (MSWI) bottom ash samples were taken from six cities of Zhejiang province, where 1/4 incinerators of China were located. The samples were instrumentally analyzed to detect the content of heavy metals. Sequential extraction procedure (SEP) was adopted to characterize the mobility and environmental impact of heavy metals. And the transfer coefficients of heavy metals from the input MSW to the bottom ash during the incineration were also calculated. It showed that the average content of Zn, Mn, Cu, Pb and Cr in the bottom ash exceeded 300 mg/kg, which was much higher than that in the soils. SEP results showed that although the residue fraction was the primary fraction of the heavy metals in the bottom ash, there were still 1.84 mg of Cd, 86.21 mg of Cu, 83.46 mg of Pb and 939.46 mg of Zn in 1 kg bottom ash having the potential of leaching, which indicated a great threat to the surrounding environment. The result of coefficients calculation revealed that almost all the Cu, Cr, Mn and Ni in the input MSW were transferred to the bottom ash during the incineration. Bottom ash was also the main destination of Cd, Co, As, Mo, Pb and Zn though considerable amounts of those metals were transferred to the raw gas.