Abstract

Polycyclic aromatic hydrocarbons (PAHs) are a class of the most common and widespread contaminants. The accumulation of PAHs has made a certain impact on the environment and is seriously threatening human health. Numerous general analytical methods suitable for PAHs were developed. With the development of economy, the environmental problems of PAHs in modern society are more extensive and prominent, and attract more attention from environmental scientists and analysts. Deeper understanding of the properties of PAHs depends on the advent of detection methods, which can also be more conducive to promoting the protection of the environment. Till now, more sensitive, more high-speed and more high-throughput analytical tools are being invented and have played important roles in the research of PAHs. In this short review article, we focused mainly on the contemporary analytical methods about PAHs. We started with a brief review on the hazards, migration, distribution and traditional analysis methods of PAHs in recent years, including liquid chromatography, gas chromatography, surface enhanced Raman spectroscopy and so on. We also presented the applications of the modern ambient mass spectrometry, especially microwave plasma torch mass spectrometry, in the detection of PAHs, as well as the far out novel results in our lab by using microwave plasma torch (MPT) mass spectrometry; for example, some new insights about Birch reduction, regular hydrogen addition and the robustness of molecular structure. These studies have demonstrated the versatility of MPT MS as a platform in the research of PAHs.

Highlights

  • After starting with a brief review on the hazards, migration, distribution and traditional analysis methods of polycyclic aromatic hydrocarbons (PAHs) which are widely used in recent years, including liquid chromatography, gas chromatography and surface enhanced Raman spectroscopy and so on, we mainly want to present the applications of the modern ambient mass spectrometry in the detection of PAHs; in addition, we present the far out novel results in our lab by using microwave plasma torch (MPT) mass spectrometry, which exhibited the versatility of MPT MS as a platform in the research of PAHs

  • There are some derived capillary electrophoresis (CE) techniques, such as micellar electrokinetic capillary chromatography (MEKC) [60,61] and parking capillary chromatography (PCC) [62], and they have been both applied in the studies of PAHs

  • Typical ambient ion source includes direct analysis in real time (DART) [102,103], surface desorption atmospheric pressure chemical ionization (DAPCI) [104,105], extractive electrospray ionization (EESI) [106–108], dielectric barrier discharge ionization (DBDI) [109], flowing atmospheric pressure afterglow (FAPA) [110], etc., all of which have obtained a series of achievements in the analysis of complex matrix samples and greatly expanded the range of analytical objects of mass spectrometry, from various fields including metabolomics [111–113], proteomics [114,115], forensic medicine [116,117], and quality monitoring [118]

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Summary

Introduction

Res. Public Health 2022, 19, 2790 stable structure, generic characteristics of PAHs are a high melting point, a high boiling point, and a low vapor pressure, and they are very difficult to metabolize and degrade in natural environment media, which leads to the accumulation of some PAHs for decades or even longer. After starting with a brief review on the hazards, migration, distribution and traditional analysis methods of PAHs which are widely used in recent years, including liquid chromatography, gas chromatography and surface enhanced Raman spectroscopy and so on, we mainly want to present the applications of the modern ambient mass spectrometry in the detection of PAHs; in addition, we present the far out novel results in our lab by using microwave plasma torch (MPT) mass spectrometry, which exhibited the versatility of MPT MS as a platform in the research of PAHs. MPT ion source is a novel ambient ion generator and has multiple advantages, for example, simple construction of the device and easy operation, low power dissipation, relative high sensitivity, and suitable for many types of samples including metal elements and organic samples [22–26]

The Spatial Distribution and Migration of PAHs
The Distribution, Migration and Harm of PAHs in Atmosphere
The Distribution, Migration and Harm of PAHs in Water
The Distribution, Migration and Harm of PAHs in Soil
Traditional Analytical Methods for PAHs
High Performance Liquid Chromatography (HPLC)
Gas Chromatography (GC)
Capillary Electrophoresis (CE)
Surface Enhanced Raman Spectroscopy (SERS)
Optical Spectrometry
Other Analytical Methods
Mass Spectrometry
MPT Mass Spectra of Benzene
Findings
Prospects
Full Text
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