Abstract

Fast growing coastal population centers face an increasing vulnerability to several emission sources of anthropogenic and industrial pollutants. The ongoing industrialization in emerging countries increases the environmental and human risk for people living in coastal megacities, especially in the global south of Asia. Extreme weather events, such as heavy rainfalls and resulting flood events, are projected to increase in frequency in the foreseen future, facing an increasing vulnerability to monsoon-induced floods and the release and distribution of xenobiotics causing harm to communities and the environment along a river’s pathway. To endeavor the unknown risks posed by these toxic floods and to assess the associated contamination distribution, the preserved organic geochemical signature from floodplain sediments is studied.This investigation evaluates the inorganic and organic pollutant assemblage in ten surface sediments along the Adyar and Cooum river in the urban areas of Chennai (southern India). Potentially toxic elements (Cr, Ni, Cu, Zn, Pb) show a continuous concentration decrease downstream. Four main groups of persistent organic pollutants have been detected: petrogenic pollutants (hopanes, PAHs), urban wastewater pollutants (LABs, DEHA, methyl-triclosan, octocrylene), technical compounds (Mesamoll®, DPE, NBFA), and pesticides (DDX). While most organic compounds show source specific properties, the definite sources for others remain vague based on the multitude of potential sources and diffusiveness of anthropogenic emissions. The chosen approaches have shown that urban wastewater pollutants and several technical compounds are suitable to assess the anthropogenic-induced contamination in floodplain sediments. However, sedimentary archives in fast-growing, urbanized environments are influenced and superimposed by anthropogenic alterations.

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