Contamination and human health risk of lead in soils around lead/zinc smelting areas in China

Abstract

Pb/Zn smelting, an important economic activity in China, has led to heavy environmental pollution. This research reviewed studies on soil Pb contamination at Pb/Zn smelting sites in China published during the period of 2000 to 2015 to clarify the total levels, spatial changes, and health risks for Pb contamination in soils at local and national scales. The results show that Pb contents in surface soils at 58 Pb/Zn smelting sites in China ranged from 7 to 312,452mgkg(-1) with an arithmetic average, geometric average, and median of 1982, 404, and 428mgkg(-1), respectively (n = 1011). Surface soil Pb content at these smelting sites decreased from an average of 2466 to 659mgkg(-1), then to 463mgkg(-1) as the distance from the smelters increased from <1000 to 1000∼2000m, and then to >2000m. With respect to variation with depth, the average soil Pb content at these sites gradually decreased from 986mgkg(-1) at 0- to 20-cm depth to 144mgkg(-1) at 80- to 100-cm depth. Approximately 78% of the soil samples (n = 1011) at the 58 Pb/Zn smelting sites were classified as having high Pb pollution levels. Approximately 34.2 and 7.7% of the soil samples (n = 1011) at the 58 Pb/Zn smelting sites might pose adverse health effects and high chronic risks to children, respectively. The Pb/Zn smelting sites in the southwest and southeast provinces of China, as well as Liaoning province, were most contaminated and thus should receive priority for remediation.