Abstract
ABSTRACT This study aims to evaluate the validity of Fractional Advection-Dispersion equation (FADE) in breakthrough curves in saturated homogenous soil media, i.e. clay, and to examine the three primary restraints, pore water velocity, dispersion coefficient, and order of fractional differentiation which are impacting solute transport behavior (Fickian or Non-Fickian). In this study, the FADE framework used to characterize the transport process at depth 50 cm soil (clay). FADE Main based on FORTRAN, to estimate the parameters of FADE including fractional differentiation (λ), the dispersive coefficient (D), and the average pore-water velocity (v). If the value of is equal to or greater than 2, the transport is said to be Fickian otherwise is non-Fickian. In this study, the fractional differentiation of non-Fickian behavior was found 1.85 which is less than 2. On the other hand, early long-time tailing to the soil media showed an increase in the dispersion coefficient (D) for FADE and higher values in differentiation coefficient (λ = 1.85–1.99). The results of breakthrough curves (BTCs) of relative concentration (C/C0) show that it is best fitted by using FADE. For the assessment of fitting, Root Mean Square Error (RMSE) and determination Coefficient was used to find the quality of fit. .
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