Abstract

Contact angles of polar liquids on various nonpolar solids immersed in a nonpolar liquid have been measured. They agreed satisfactorily with values calculated by combining Young's equation either with measured contact angle data of the liquids on the substrates in air, or with the Fowkes relation valid at each of the interfaces. The latter method also applies when one of the liquids spreads on the substrate in air. Polyethene, polystyrene, polytetrafluorethene and glyceryltristearate were used as nonpolar solids; paraffin oil and heptane as nonpolar liquids; water and glycerol as polar liquids.

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