Abstract
Reactions of thiomolybdate or thiotungstate [MOS 3] 2− (M = Mo, W) with 3 equiv. of CuS 2P(OMe) 2 led to the formation of two novel Mo(W)/Cu/S polymers [Et 4N][MOS 3Cu 3{S 2P(OMe) 2} 2] ( 1, M = Mo; 2, M = W). Single-crystal X-ray diffraction studies reveal that 1 and 2 are the first examples that containing anionic 2D (6,3) net with nest-shaped [MOS 3Cu 3 · S 2P(OMe) 2] clusters as 3-connecting nodes and tridentate [S 2P(OMe) 2] − ligands as linkers. Both 1 and 2 crystallize in a noncentrosymmetric space group and the former polymer shows good second-order NLO performance.
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