Abstract
AbstractTwo mixed‐ligand coordination polymers (CPs) based on a biphenyl‐based dicarboxylate ligand and 4,4′‐bipyridine or imidazole co‐ligand, namely, [Co(DMBDA)(bpy)]n (1) (H2DMBDA = 2,2′‐dimethylbiphenyl‐4,4′‐dicarboxylic acid, bpy = 4,4′‐bipyridine) and [Zn(DMBDA)(Im)]n (2) (Im = imidazole), were obtained under hydrothermal conditions. Compound 1 exhibits a new (4,6)‐connected network with a {44·610·8}{44·62} Schläfli symbol, whereas compound 2 shows a 4‐connected NbO‐type topology. These coordination polymers represent two rare examples of CPs based on 2,2′‐dimethylbiphenyl‐4,4′‐dicarboxylic acid. The solid‐state luminescent behaviors of the novel CPs were also investigated at room temperature.
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More From: Zeitschrift für anorganische und allgemeine Chemie
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