Construction of superhydrophobic tungsten carbide via laser processing and its thermal, chemical and mechanical properties

Abstract

Designing microscale microstructures on superhard materials and achieving superhydrophobic surfaces through wettability adjustment have promising application prospects. However, current popular methods for preparing superhydrophobic surfaces have not designed and optimized the microstructures, and achieving superhydrophobicity on superhard materials using conventional industrial methods remains a tremendously challenge. Here, we propose a novel multiscale microstructure design on superhard tungsten carbide (WC) alloy material, achieved through laser processing, which exhibits superhydrophobicity after low surface energy modification. To ensure the designed microstructures possesses excellent mechanical strength and wettability, the influence of size parameters on mechanical strength and their relationship with wettability through finite element analysis (Abaqus) and characterization techniques were conducted. Based on the optimized robust multiscale structure, we also investigated the comprehensive properties of the superhydrophobic surface. The thermal, chemical, and mechanical stability of the WC superhydrophobic surface were explored through experiments involving temperature exposure, immersion in acid-base solutions, friction and wear tests. Our findings demonstrate that the superhydrophobic WC surface exhibits excellent temperature resistance over a wide range, maintaining superior water repellency even after prolonged exposure to chemical solutions and mechanical abrasion tests. In addition, the substrate's microstructure and SiO2 nanoparticles successfully replicated on the optical glass surface through molding technology, creating a consistently superhydrophobic glass microstructure. This work provides a new perspective for designing superhard alloy materials with robust microstructures and offers potential for a series of applications, such as mold, semiconductor and solar cell.