Abstract
A metal-coordination-driven self-assembly using the predesigned building block has been developed. Herein, the catalytic active NHC–Cu(I) units were introduced into the terpyridine metal coordination polymers. The self-assembled architecture, as a heterogeneous catalyst, was successfully used to catalyze the A3-coupling reaction of aldehyde, alkyne, and amine and Huisgen 1,3-dipolar cycloaddition reaction of azide and alkyne in high yields.
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