Construction of oxygen vacancies and heterostructure in VO2-x/NC with enhanced reversible capacity, accelerated redox kinetics, and stable cycling life for sodium ion storage

Abstract

Developing anode materials with high reversible capacity, fast redox kinetics, and stable cycling life for Na+ storage remains a great challenge. Herein, the VO2 nanobelts with oxygen vacancies supported on nitrogen-doped carbon nanosheets (VO2-x/NC) were developed. Benefitting from the enhanced electrical conductivity, the accelerated kinetics, the increased active sites as well as the constructed 2D heterostructure, the VO2-x/NC delivered extraordinary Na+ storage performance in half/full battery. Theoretical calculations (DFT) demonstrated that oxygen vacancies could regulate the adsorption ability for Na+, enhance electronic conductivity, as well as achieve rapid and reversible Na+ adsorption/desorption. The VO2-x/NC exhibited high Na+ storage capacity of 270 mAh g−1 at 0.2 A g−1, and impressive cyclic stability with 258 mAh g−1 after 1800 cycles at 10 A g−1. The assembled sodium-ion hybrid capacitors (SIHCs) could achieve maximum energy density/power output of 122 Wh kg−1/9985 W kg−1, ultralong cycling life with 88.4% capacity retention after 25,000 cycles at 2 A g−1, and practical applications (55 LEDs could be actuated for 10 min), promising to be utilized in a practicable Na+ storage.