Abstract
Three Cd(II)-based coordination polymers 1–3 with unique structures and topologies have been successfully constructed under solvothermal conditions by use of a newly designed N-containing rigid triangular ligand tris(4-(4H-1,2,4-triazol-4-yl)phenyl)amine (TTPA-4), wherein the structural interpenetration can be modulated by aromatic dicarboxylate coligands including thiophene-2,5-dicarboxylic acid (TDA) and terephthalic acid (TPA). Without using coligands, a noninterpenetrating porous 3-D network of 1 with nia topology was obtained. With the aid of the V-shaped TDA coligand, a 4-fold interpenetrating 3-D network of 2 resulted that is built from (2,3,7)-connecting (42.6)(44.6.88.104.124)(4)2 net. In the presence of the linear TPA auxiliary ligand, an 8-fold interpenetrating 3-D network of 3 was produced that is assembled by 3-connecting uninodal srs net. Particularly, compound 1 displays interesting dual function as the result of its unique structural attributes, which not only shows superb sensitivity for ...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.