Abstract
AbstractA series of substituted nitrogen‐containing 9‐membered epoxy vinyl ethers has been constructed from easily available 5‐aza‐2,3‐epoxy‐7‐yn‐1‐ols. Attack of the hydroxyl group onto the gold(I)‐activated alkyne gave the postulated 9‐membered allylic vinyl ether gold intermediate which underwent protodeauration affording the 9‐membered epoxy vinyl ethers.
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