Construction of multifunctional NH2-UiO-66 metal organic framework: sensing and photocatalytic degradation of ketorolac tromethamine and tetracycline in aqueous medium.

Abstract

Existence of pharmaceutical residues in water has endangered environmental pollution worldwide, which makes it ineludible to develop prospective bifunctional materials which not only possess excellent fluorescence behaviour to monitor pharmaceuticals but also exhibit simultaneous photocatalytic removal efficiency. Strengthened by functionalized metal organic framework (MOF) materials, we present here an amine functionalized zirconium-based MOF NH2-UiO-66 which has been successfully synthesized using solvothermal approach. The as prepared MOF was subjected to numerous structural, morphological and compositional characterizations. Interestingly, featured by the excellent fluorescent intensity of MOF modulated by LMCT effect, NH2-UiO-66 was screened to detect pharmaceutical compounds with KTC and TC in aqueous solution. The prepared functionalized MOF showcased excellent sensing platform with magnificent response range (0‒3µM), lower limit of detection (160nM; KTC and 140nM; TC), excellent selectivity and influential anti-interference capability. More importantly, the practical utility of the proposed sensor was further explored for the determination of pharmaceutical drugs in real water samples with suitable recoveries. Simultaneously, the synthesized MOF also exhibited high photocatalytic efficiency towards the removal of KTC and TC under solar light irradiation. The degradation efficiency for KTC and TC was found to be 68.3% and 71.8% within 60 and 280min of solar light, respectively. Moreover, excellent recyclability was demonstrated by the current synthesized system over five cycles. Overall, this study presents a feasible route for the utilization of functionalized MOFs as potential dual functional materials towards the simultaneous detection and degradation of specific pharmaceuticals from aqueous medium.